Men's Work and Safety Boots and Shoes. Men's work and safety boots and shoes give added durability and protection for all your industrial needs. Available in safety toe and non safety toe styles. Soles of these shoes are usually slip resistant and oil resistant depending on the work environment. Men's work shoes also come in Electrical Hazard and Static Dissipative and Metatarsal Guard models. Choose from these top name brands in mens work and safety boots and shoes, including Skechers, Carolina, Timberland Pro, Nautilus, Doc Martens, Keen Utility and more.